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# Thermodiffusion effects on magneto-nanofluid flow over a stretching sheet

*Boundary Value Problems*
**volume 2013**, Article number: 136 (2013)

## Abstract

We study the effect of thermophoresis on boundary layer magneto-nanofluid flow over a stretching sheet. The model includes the effects of Brownian motion and cross-diffusion effects. The governing partial differential equations are transformed to a system of ordinary differential equations and solved numerically using a spectral linearisation method. The effects of the magnetic influence number, the Prandtl number, Lewis number, the Brownian motion parameter, thermophoresis parameter, the modified Dufour parameter and the Dufour-solutal Lewis number on the fluid properties as well as on the heat, regular and nano mass transfer coefficients are determined and shown graphically.

## 1 Introduction

Most common fluids such as water, ethylene, glycol, toluene or oil generally have poor heat transfer characteristics owing to their low thermal conductivity. A recent technique to improve the thermal conductivity of these fluids is to suspend nano-sized metallic particles such as aluminum, titanium, gold, copper, iron or their oxides in the fluid to enhance its thermal properties, Choi [1]. The enhancement of thermal conductivity in nanofluids has been studied by, among others, Kakac and Pramuanjaroenkij [2], Choi *et al.* [3], Masuda *et al.* [4], Eapen *et al.* [5] and Fan and Wang [6]. Nield and Kuznetsov [7] analyzed the behaviour of boundary layer flow on the Chen-Minkowycz problem in a porous layer saturated with a nanofluid. Nield and Kuznetsov [8] investigated thermal instability in a porous medium saturated with nanofluid using the Brinkman model. The model incorporated the effects of Brownian motion and thermophoresis of nanoparticles. They found that the critical thermal Rayleigh number can be reduced or increased by a substantial amount depending on whether the nanoparticle distribution is top-heavy or bottom-heavy. Aziz *et al.* [9] studied steady boundary layer flow past a horizontal flat plate embedded in a porous medium filled with a water-based nanofluid containing gyrotactic microorganisms. Cheng [10] investigated the behaviour of boundary layer flow over a horizontal cylinder of elliptic cross section in a porous medium saturated with a nanofluid. Chamkha *et al.* [11] investigated the non-similar solutions for natural convective boundary layer flow over a sphere embedded in a porous medium saturated with a nanofluid.

During the last few decades, fluid flow over a stretching surface has received considerable attention because of its engineering applications such as in melt-spinning, hot rolling, wire drawing, glass-fiber production and the manufacture of polymer and rubber sheets, Altan and Gegel [12], Fisher [13], and Tidmore and Klein [14]. Nanofluid flow over a stretching surface has been investigated by many researchers. The first study on a stretching sheet in nanofluids was published by Khan and Pop [15]. Makinde and Aziz [16] performed a numerical study of boundary layer flow over a linear stretching sheet. Both Brownian motion and thermophoresis effects on the transport equations were presented. They reported that stronger Brownian motion and thermophoresis lead to an increase in the rate of heat transfer. However, the opposite was observed in the case of the rate of mass transfer. Recent studies in this area include those of Narayana and Sibanda [17] and Kameswaran *et al.* [18].

Magnetic nanofluids have numerous uses or potential applications in engineering and medicine. Using magnetic nanofluids has the potential to regulate the flow rate and heat transfer by controlling the thermo-magnetic convection current and the fluid velocity (see Shima *et al.* [19], Ganguly *et al.* [20]). The effects of a magnetic field on nanofluid flow over a stretching sheet have been investigated by, among others, Bachok *et al.* [21] and Hanad and Ferdows [22].

The aim of this study is to analyse Dufour and Soret effects in a magneto-nanofluid flow over a stretching sheet. In addition, we study Brownian motion and thermophoresis effects using a spectral linearisation method to obtain numerical solutions of the momentum, energy, concentration and mass fraction equations. The successive linearisation method (SLM) is an accurate method for solving non-linear coupled equations (see [23–25]). Recent studies such as [26–28] have suggested that the SLM is accurate and converges rapidly to the numerical results when compared to other semi-analytical methods such as the Adomian decomposition method, the variational iteration method and the homotopy perturbation method.

## 2 Mathematical formulation

Consider two-dimensional nanofluid flow over a linearly stretching sheet with velocity {u}_{w}=ax, where *a* is a real positive number. The coordinate system is assumed to define the *x*-axis along the surface of the sheet and *y* is the coordinate normal to the surface of the sheet. The surface temperature {T}_{w} and nanoparticle concentration {\stackrel{\u02c6}{\varphi}}_{w} are higher than the ambient values {T}_{\mathrm{\infty}} and {\stackrel{\u02c6}{\varphi}}_{\mathrm{\infty}}, respectively. The governing equations for the problem can be written in the form

with the boundary conditions

where *u* and *v* are the velocity components along the *x* and *y* direction respectively, *σ* is the electrical conductivity, {B}_{0} is magnetic field flux density, *ν* kinematic viscosity of the base fluid, *α* is the thermal diffusivity of the porous medium, {D}_{B} is the Brownian diffusion coefficient, {D}_{T} is thermophoresis diffusion coefficient, {D}_{CT} and {D}_{TC} are the Soret and Dufour diffusivities, {D}_{S} is the solutal diffusivity, *T* is the fluid temperature, *C* is the solutal concentration, \stackrel{\u02c6}{\varphi} is the nanoparticle volume fraction, {(\rho c)}_{f} and {(\rho c)}_{p} are the heat capacity of the fluid and the effective heat capacity of the nanoparticle material respectively, *τ* is a parameter defined by {(\rho c)}_{f}/{(\rho c)}_{P}. Using the similarity variables

equations (1)-(5) reduce to the following non-similar forms where primes denote differentiation with respect to *η*:

subject to the boundary conditions

The parameters in equations (8)-(11) are the magnetic number *M*, the Prandtl number *Pr*, the Lewis number *Le*, the Brownian motion parameter *Nb*, the thermophoresis parameter *Nt*, the nanofluid Lewis number *Ln*, the modified Dufour parameter *Nd* and the Dufour-solutal Lewis number *Ld*. These parameters are defined as

The parameters of engineering interest in heat and mass transport problems are the local Nusselt number {\mathit{Nu}}_{x}, the Sherwood number {\mathit{Sh}}_{x} and the nanofluid Sherwood number {\mathit{Sh}}_{x,n}. These parameters characterise the wall heat, the regular and nano mass transfer rates, respectively, and are defined by

Following Khan and Aziz [29], the physical parameters of interest are the reduced Nusselt *Nur*, the Sherwood number \stackrel{\u02c6}{\mathit{Sh}} and the reduced Sherwood *Shr* defined as

## 3 Method of solution

The system of equations (8)-(11) together with the boundary conditions (12) were solved using the successive linearisation method (SLM) (see [25, 26, 30]). The unknown functions f(\eta ), \theta (\eta ), S(\eta ) and \varphi (\eta ) are expanded as

where {f}_{i}, {\theta}_{i}, {S}_{i} and {\varphi}_{i} are unknown and {F}_{m}, {\mathrm{\Theta}}_{m}, {\tilde{S}}_{m} and {\mathrm{\Phi}}_{m} (m\ge 1) are successive approximations that are obtained by recursively solving the linear forms of the equation system that results from substituting (13) into equations (8)-(11). In particular, the linearised equations to be solved are

subject to the boundary conditions

where coefficient parameters {a}_{k,i-1}, {b}_{k,i-1}, {c}_{k,i-1}, {d}_{k,i-1} (k=1,\dots ,4) and {r}_{j,i-1} (j=1,\dots ,4) are known constants. The initial guesses {F}_{0}(\eta ), {\mathrm{\Theta}}_{0}(\eta ), {\tilde{S}}_{0}(\eta ) and {\mathrm{\Phi}}_{0}(\eta ) are chosen to satisfy the boundary conditions

and are chosen as

Starting from the initial guesses and iterating {M}_{1} times, the functions f(\eta ), \theta (\eta ) and \varphi (\eta ) are written as

where {M}_{1} is the order of the SLM approximation. Equations (14)-(17) are solved using the Chebyshev spectral collocation method. The method is based on the Chebyshev polynomials defined on the interval [-1,1]. We first transform the domain of solution [0,\mathrm{\infty}) into the domain [-1,1] using the domain truncation technique where the problem is solved in the interval [0,L] where *L* is a scaling parameter used to invoke the boundary condition at infinity. This is achieved by using the mapping

We discretise the domain [-1,1] using the Gauss-Lobatto collocation points given by

where *N* is the number of collocation points used. The functions {F}_{i}, {\mathrm{\Theta}}_{i}, {\tilde{S}}_{i} and {\mathrm{\Phi}}_{i} for i\ge 1 are approximated at the collocation points as follows:

where {T}_{k} is the *k* th Chebyshev polynomial given by

The derivatives of the variables evaluated at the collocation points \xi ={\xi}_{j} are represented as

where *r* is the order of differentiation and \mathbf{D}=\frac{2}{L}\mathcal{D} with \mathcal{D} being the Chebyshev spectral differentiation matrix (see, for example, [31–33]), whose entries are defined as

Substituting equations (22)-(26) into equations (14)-(17) leads to the matrix equation

where {\mathbf{A}}_{i-1} is a (4N+4)\times (4N+4) square matrix and {\mathbf{X}}_{i} and {\mathbf{R}}_{i-1} are (4N+4)\times 1 column vectors defined by

The functions and parameters in equation (29) are

In the definitions above, *T* stands for transpose, {\mathbf{a}}_{k,i-1} (k=1,\dots ,3), {\mathbf{b}}_{k,i-1} (k=1,\dots ,4), {\mathbf{c}}_{k,i-1} (k=1,\dots ,3), {\mathbf{d}}_{k,i-1} (k=1,\dots ,3) and {\mathbf{r}}_{k,i-1} (k=1,\dots ,4) are diagonal matrices of order (N+1)\times (N+1), **I** is an identity matrix of order (N+1)\times (N+1) and [\mathbf{0}] is a zero matrix of order (N+1)\times (N+1). The solution is obtained as

## 4 Results and discussion

In this section we present solutions of equations (8)-(11) along with the boundary conditions (12) using the SLM iteration scheme. Tables 1 and 2 give a comparison between the present results and Khan and Pop [15] for the reduced Nusselt and Sherwood numbers respectively. There is a good agreement between the two sets of results with the SLM having converged at the fourth order up to eleven decimal places. The velocity components f(\eta ) and {f}^{\prime}(\eta ) are plotted in Figures 1(a) and 1(b) for different values of the magnetic field parameter *M*. As is now well known, the velocity decreases with increases in the magnetic field parameter due to an increase in the Lorentz drag force that opposes the fluid motion.

Figures 2(a) and 2(b) show the effect of the thermophoresis parameter on the temperature and mass volume fraction profiles. The thermophoretic force generated by the temperature gradient creates a fast flow away from the stretching surface. In this way more fluid is heated away from the surface, and consequently, as *Nt* increases, the temperature within the boundary layer increases. The fast flow from the stretching sheet carries with it nanoparticles leading to an increase in the mass volume fraction boundary layer thickness.

Figures 3(a) and 3(b) show the effect of the Lewis number *Le*, and the Dufour-solutal Lewis number *Ld* on the species concentration in the boundary layer. The concentration profiles significantly contract as the Lewis number increases. The effect of the random motion of the nanoparticles suspended in the fluid on the temperature and nanoparticle volume fraction is shown in Figures 4(a) and 4(b). As expected, the increased Brownian motion of the nanoparticles carries with it heat and the thickness of the thermal boundary layer increases. The Brownian motion of the nanoparticles increases thermal transport which is an important mechanism for the enhancement of thermal conductivity of nanofluids. However, we note that increasing the Brownian motion parameter leads to a clustering of the nanoparticles near the stretching sheet. An increase in the Brownian motion of the nanoparticles leads to a decrease in the mass volume fraction profiles.

Figures 5(a) and 5(b) show the temperature profiles for several values of the Prandtl number *Pr* and mass volume fraction profile for several values of the modified Dufour number *Nd*. The temperature profiles decrease as the Prandtl number increases since, for high Prandtl numbers, the flow is governed by momentum and viscous diffusion rather than thermal diffusion. On the other hand, the thickness of the mass volume fraction boundary layer increases with an increase in *Nd*.

Figures 6(a) and 6(b) show the effects of the thermophoresis parameter *Nt*, the Lewis number *Le*, the magnetic field parameter *M*, the Prandtl number *Pr* and the modified Dufour number *Nd* on the wall heat and mass fraction transfer rates. It can be seen that the thermal boundary layer thickness increases when the thermophoresis parameter *Nt* increases, thus decreasing the reduced Nusselt number. However, increasing the Lewis number *Le* leads to a decrease in the reduced Nusselt number. On the other hand, the results show that the reduced Nusselt number increases with increasing Prandtl numbers. Increasing both the magnetic field parameter *M* and the modified Dufour parameter *Nd* leads to an increase in the thermal boundary layer thickness, thus reducing the Nusselt number.

Figures 7(a) and 7(b) show the effects of the Dufour-solutal Lewis number *Ld* and the nanofluid Lewis number *Ln* on the reduced Nusselt number *Nur* as the Brownian motion parameter *Nb* increases. We note a decrease in the reduced Nusselt number when *Ln* increases, and an increase in the reduced Nusselt number when *Ld* increases.

Figures 8(a) and 8(b) show the graphs of -{\theta}^{\prime}(0) and {S}^{\prime}(0) plotted against the Dufour-solutal Lewis number *Ld* for different values of the parameters *Nt*, *Nb* and *Le*. We observe that -{\theta}^{\prime}(0) increases in the absence of the Brownian motion and the thermophoresis parameter while -{\theta}^{\prime}(0) decreases in the presence of Brownian motion and thermophoresis parameters. An increase in -{S}^{\prime}(0) is observed in the presence of both the Brownian motion and the thermophoresis parameter. Figures 9(a) and 9(b) show the effect of increasing *Nt* and *Nb* respectively on the reduced Sherwood number -\varphi (0).

## 5 Conclusions

A numerical study of the magneto-nanofluid boundary layer flow over a stretching sheet was carried out. We determined the effects of various parameters on the fluid properties as well as on the heat, and the regular and nano mass transfer rates. We have shown that increasing the magnetic field parameter *M* tends to retard the fluid flow within the boundary layer. The effects of the Prandtl number, the Lewis number, the Brownian motion parameter, the thermophoresis parameter, the nanofluid Lewis number, the modified Dufour parameter and the Dufour-solutal Lewis number on the heat, regular and nano mass transfer coefficients and fluid flow characteristics have been studied. We have shown *inter alia* that:

– the thermal boundary layer thickness increases with the thermophoresis parameter;

– increasing the Lewis number reduces the heat transfer coefficient;

– the heat transfer coefficient increases in the absence of the Brownian motion and the thermophoresis parameter and decreases in the presence of Brownian motion and thermophoresis parameters.

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## Acknowledgements

The authors wish to thank the University of KwaZulu-Natal for financial support.

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Awad, F.G., Sibanda, P. & Khidir, A.A. Thermodiffusion effects on magneto-nanofluid flow over a stretching sheet.
*Bound Value Probl* **2013**, 136 (2013). https://doi.org/10.1186/1687-2770-2013-136

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DOI: https://doi.org/10.1186/1687-2770-2013-136